Thứ Ba, 31 tháng 1, 2017
Youtube daily auto Jan 31 2017
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Trump-Auto steht demnächst zum Verkauf - Duration: 2:33.
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Betonmischer für Kinder. Farbige Auto. Trickfilme Betonmischer. Zug für Kinder. Kinderfilm autos. - Duration: 11:06.
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Hormigonera para niños. Сoche de color Colores para los niños Hombre araña y auto cars Tren infantil - Duration: 11:05.
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Fiat Doblò Cargo 1.3 MultiJet SX, Airco, Schuifdeur rechts, Zeer nette auto!! - Duration: 1:14.
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Nissan QASHQAI 1.6 VISIA Airco Cruise Navi 91.000km NAP NL-Auto '11 - Duration: 1:38.
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Renault Laguna Estate 2.0 16V DYNAMQUE Super mooie auto - Duration: 1:11.
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Peugeot 206 2.0-16V GTI, LEDER, CLIMA, LMV * NETTE AUTO* - Duration: 0:59.
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Mitsubishi Space Star 1.9 DI-D FAMILY NETTE BETROUWBARE AUTO - Duration: 1:24.
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Volkswagen up! 1.0 MOVE UP! BLUEMOTION Navi/ Airco/ Bluetooth NL auto - Duration: 1:02.
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Renault Modus 1.4-16V AIR, Aico, cruise control. Keurige auto - Duration: 1:08.
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Volkswagen up! 1.0 MOVE UP! BLUEMOTION Navi/ Airco/ Bluetooth NL auto - Duration: 1:33.
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What Is An Damage Repair Estimate? - Auto Estimating Part 1 - Duration: 15:04.
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Volkswagen Golf 1.4 TSI HIGHLINE NL AUTO!! AUTOMAAT Climate/Nav/ - Duration: 1:22.
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Suzuki Splash 1.0 VVT BASE 5 Deurs *Keurige Auto* 38.000km! '12 - Duration: 1:19.
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Porsche Cayenne TURBO 4.8 V8 TIPTRONIC S NL-Auto - Duration: 0:42.
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Kodiaq 2016 zamów już dziś w Ultima Auto - Duration: 1:48.
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Nissan Micra 1.2 TEKNA Zuinig en mooie auto met airco - Duration: 0:51.
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Ford Mondeo Wagon 2.0-16V LIMITED *Navi*Pdc*Nette auto* - Duration: 1:07.
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Renault Laguna Estate 2.0 16V DYNAMQUE Super mooie auto - Duration: 1:23.
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This field is auto filled - Duration: 2:57.
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Youtube daily song Jan 31 2017
♪ This is my happy song ♪
♪ And I can sing it all day long ♪
- ♪ Playing with my family makes me happy ♪
♪ And when I'm happy I like to clap ♪
♪ I'll clap to the left and clap to the right ♪
- (all): ♪ Clap to the left ♪
♪ And clap to the right ♪
- ♪ Pretending makes me happy ♪
♪ And when I'm happy I like to jump ♪
♪ I'll jump to the left and jump to the right ♪
- (all): ♪ Jump to the left ♪
♪ And jump to the right ♪
♪ This is my happy song ♪
♪ And I can sing it all day long ♪
- ♪ Music makes me happy ♪
♪ And when I'm happy I like to dance ♪
♪ I'll dance to the left and dance to the right ♪
- (all): ♪ Dance to the left ♪
♪ And dance to the right ♪
♪ This is my happy song ♪
♪ And I can sing it all day long ♪♪
For more infomation >> DANIEL TIGER'S NEIGHBORHOOD | Clap, Jump and Dance the Happy Song | PBS KIDS - Duration: 1:18.-------------------------------------------
FRIED CHICKEN SONG!!! (ROBLOX) - Duration: 2:06.
Fried Chicken! I Never Stop Eating This Stuff It's So Tasty
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Robert Stearns sings this powerful song at the World Conference! - Duration: 12:01.
I want to invite you right now to come with me tonight to the city where it all began
and the city of our glorious hope, the city of Jerusalem!
Walking down the road in Jerusalem today.
The time has come for us to sacrifice again.
My two little boys they walked beside me
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Learn Colors with Coca-Cola Finger Family Songs for Children Toddlers and Babies | Nursery Rhymes - Duration: 3:57.
Learn Colors with Coca-Cola Finger Family Songs for Children Toddlers and Babies | Nursery Rhymes
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Champesaave Nannu Song Promo 720P HD - Duration: 0:45.
ABCD ANII LETTERS RAASI
LOVE ANII RAASI
CHAMPESAAAAAAAVEEEE
NANNU
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Spiderman and Lightning McQueen MONSTER TRUCK in Cars Cartoon | Songs for Kids and Children - Duration: 12:27.
Spiderman and Lightning McQueen MONSTER TRUCK in Cars Cartoon | Songs for Kids and Children
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桜 (Sakura)- Piano and Vocals Only (Original Song) - Duration: 2:52.
Take two! Haha
'Twas a day in late April, it was almost May
When I logged onto YouTube, unknowingly
Went to a channel, clicked on a video, and
In that moment my life changed
As I heard the words roll smoothly, as if they had been sung
From an unfamiliar face, in an unfamiliar tongue
I knew, I knew, what I had to do
I was going to get there, determined through and through
さくら、さくら、さくらさん
I've got a goal, and I've got a plan
The happiness that's ensued, has brightened up my life
And I realized that sometimes things take time to get right
So I took a step back and asked, "where do I start?"
I've got a dream, and I'll reach for the stars
I studied and studied, it turned into a passion
Bad feelings finally began to pass on
And I said...
さくら、さくら、さくらさん
I've got a goal, and I've got a plan
The happiness that's ensued, has brightened up my life
And I realized that sometimes things take time to get right
Yeah, I realized that sometimes thing take time to get right
*my beautiful cat meows*
Me: Oh my goodness, I keep messing this up (*cat meows*)
*cat meows again*
*cat meows yet again*
*two more meows from the wonderful cat*
From an- *bursts into laughter*...cat
*laughs*
*laughs again*
Heard the words roll-
Okay
*sound of frustration repeated a few times at different speeds*
I'm starting all over again
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Koi Rohi Yad Krendi ShafaUllah Rokhri Zeeshan Khan Rokhri 2017 Saraiki New Song - Duration: 7:10.
Please SubsCribe My Channel Rj Ayesha Shehzadi
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Lollipops Finger Family Song for kids|children|babies|toddlers|Daddy finger song - Duration: 23:25.
For more infomation >> Lollipops Finger Family Song for kids|children|babies|toddlers|Daddy finger song - Duration: 23:25. -------------------------------------------
FACUNDO EXE song control complete TLT - Duration: 2:49.
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Left Brain Right Brain ACTUAL Animation (Burnham) - Duration: 4:40.
This is Bo's Left Brain
Objective,
Logical,
Cold,
Analytical...
Aware of patterns.
Aware of trends.
He's efficient...
And a prick.
This is Bo's Right Brain
Subjective,
Creative,
Sensory,
Aware of feelings.
Aware of people.
He's emotional...
And an idiot.
That's your opinion. Just, careful with opinions
Okay boys...
Play nice.
I am the Left Brain, I am the Left Brain
I work really hard til' my inevitable death brain
You got a job to do, you better do it right
And the right way, is with the Left Brain's might
I like oreos and pussy
YES!
In that order!
And I cried for at least an hour
after watching Toy Story 3
WOODY!
I am the Right Brain
I have feelings
I'm a little all over the place,
But I'm lustful,
trustful,
and I'm looking for somebody to love...
Or put my penis in ( ͡° ͜ʖ ͡°)
Here comes a female, here comes a female
Puff your chest out, take your phone and check your email
Our evolutionary purpose is repopulate,
so gather data now and see if she's a possible mate.
Holy fuck!
I think she might be the one!
There's something about her...
I just can't describe it!
Tits
I am the Earth, she's the glorious sun
I want her to trust me...
And I just want her to
How do I say this?
Sit on my face?
Sit! SIT ON MY FACE!
Alright now Right Brain, you're being insane
No Left Brain
I'm just being a alive
You should try it...
You might like it!
I worked hard to give him everything he cared about
You were worried about the things that he was scared about
I'm calm and collected when you act wild
I am the adult, you are the child!
You think you're the right one every time
You think you know everything...
But you don't know anything... at all
Half of his problems were supposed to be, mine
But you wanted everything
I hope that you're happy...
Cuz' he's sure not
Well according to my calculations, I'm sorry let me run the numbers again...
um...
You're a pussy!
Name calling, really, you're gonna just do name calling?
I'm not calling names, alright, I'm stating facts. And the fact is...
You're a quivering pussy
I'm the pussy?
Well at least I don't play with toys still, okay?
Rubik's cubes are not toys! They keep my spatial reasoning skills...
sharp!
Left Brain plays with toys! Look at you!
Mister...
You're a... toy player!
Well at least I did my fucking job, alright!?
I kept him working,
I kept him productive
You were supposed to look after him!
You were supposed to keep him emotionally stable through all this!
Now you're trying to blame me for how he's feeling, how he's feeling!
If he's feeling unhappy it's because you failed him!
You did this to him, he hates you, I know he does!
HE FUCKING HATES YOU!
Right Brain, look, I'm sorry. Okay?
No you're not
Look,
Maybe there's something that...
We could do... together
Together?
Take the best parts of both of us...
Put em' together
I'm listening
It would let you let your feelings out,
It would let me analyze
So you could man the themes, I'll man the form
It's something the George Carlin did
It's something that Steve Martin did
It's something special that we could both, perform
Do you know what it is?
Juggling!
We could juggle, and juggle our cares away!
itwas
It was comedy!
We could do... comedy together and -
*Initiate Reassembly*
Alright, Right Brain look,
We're gonna do comedy together, alright?
We gotta do comedy!
Alright, alright Left Brain we'll do comedy
We can- Look, we can fix him like this
We can make him happy again, I promise, alright?
Left Brain!
Left Brain I love you!
I know
*Experimentation complete*
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saraswati puja 2017 date/ saraswati puja song/ saraswati puja mantra/ saraswati puja image. - Duration: 2:19.
Basant Panchami 2017: Saraswati Puja Date and Time (Muhrat).
Happy Basant Panchami 2017! This is the day which marks the end of winters and the slow beginning of spring. The word 'basant' means spring and 'panchami' refers to the fifth day of Magh month, on which day this festival falls every year.
This festival also celebrates the birth of Goddess Saraswati, the Goddess of knowledge, education, art, culture and music. Saraswati Puja is an important festival in India, particularly across the Eastern states.
You will find almost every family getting together to clean their house and perform the auspicious puja for the Goddess to bless the children with good knowledge.
It is believed that with the Goddess's blessings, the children will be able to excel at their studies and extra-curricular activities like art and music.
Saraswati Puja Alpana refers to the sacred offering made to the Goddess a day before Basant Panchami, with the belief that she would join in the celebrations by attending the traditional feast the following morning.
What is the Saraswati Puja (Muhrat)time? Saraswati Puja time and date (more commonly known as Muhrat) are supposed to coincide with Panchami Tithi.
The puja is usually performed in the morning, between sunrise and midday. The most auspicious time is from 7:12 am to 12:34 pm. And this year, it falls on 1st February.
The puja is performed not only in the households but also in schools, colleges and other educational Institutions. Of course no Indian festival is complete without delicious traditional sweets to ring in the celebrations.
Fresh fruits like bananas and apples are also included in the prasad along with other regional treats.
Please subscribe to the channel to watch the news or in the country and internationally. Sincerely and respectfully.
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Nursery Rhymes |Animated Kids Rhymes Collection for children| Rhymes | Kids songs| Slate Kids Rhymes - Duration: 7:48.
For more infomation >> Nursery Rhymes |Animated Kids Rhymes Collection for children| Rhymes | Kids songs| Slate Kids Rhymes - Duration: 7:48. -------------------------------------------
Peppa Pig Superman family finger songs and more nursery rhymes and baby songs. Dancing Kids TV - Duration: 13:57.
Daddy finger, daddy finger, where are you?
Here I am, here I am. How do you do?
Mommy finger, Mommy finger, where are you?
Here I am, here I am. How do you do?
Brother finger, Brother finger, where are you?
Here I am, here I am. How do you do?
Sister finger, Sister finger, where are you?
Here I am, here I am. How do you do?
Baby finger, Baby finger, where are you?
Here I am, here I am. How do you do?
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How to Apply Mix Coordinations Into Songs - Duration: 6:10.
have you been struggling with applying
mix coordinations into your songs that
is what we're going to talk about today
in this tip I'm Shelby Rollins with
Singing Success and i can tell you that
one of the number one questions that i
get from my students at the end of
usually the first one or two lessons is
ok ok i can make these weird noises but
how do i sing a song which the
million-dollar question and for one you do
have to kind of be patient with the
process
trust me a little bit here but that's
what we're going to really dig into is
how do we take these exercises these
wild sounds even the normal sounds and
actually put it into a song couple
things you have to remember and take
into consideration here is when you sing
a song it's innately harder than
singing a scale and the reason is even
free vocalizing is the easiest version
because you're just making noise you're
not thinking about pitch you're not
thinking about quality it's just like a
meow whatever
when you put that into a scale you've
actually come to another level of
application because now you're having to
discipline the pitch from just meow to
meow or something like that where
you actually hear disciplined notes and
a scale and then when you go into a song
it's a whole nother level again because
now you're changing from the same
syllable over and over again to lyrics
that are not the same and not always as
friendly as the syllables that we use in
the programs and in our lessons in this
methodology and then you're also adding
dynamics you're adding crescendo
decrescendo you're adding then the
million-dollar one is emotion you're
adding feelings you're adding emotion
connecting to an audience and
elevating your lyrics to something that
can relate to somebody else and you know
we usually don't do that much when it
comes to a meow and a scale we don't put
a lot of emotion into that usually on
purpose because we kind of need to think
a little bit differently in those
moments so let's take a meow for example
and see if we can workshop that into an
example of singing High singing that belty
range into a phrase of the song so if
I'm singing (meow sounds) and I
need to get into something right around
that
range but I keep pulling up chest or I
can't really quite get that same sound
then the first thing I usually do with a
student in a lesson is have them take
the most successful syllable that
they're using in a scale and replace the
song lyric with that syllable so instead
of singing for instance the lyrics to a
song i'm going to put the meow in here
instead go (meow sounds) and just sort
of fall off of it
forget finesse forget quality here i did add
a little bit of vibrato because I was
already doing that before but i can go
from there to (meow sounds) and get myself
into a song lyric and I don't even
though the cry word is different from
the meow the word cry actually is asking
for me to put that kind of resonance
into it and I want the meow to inform
the cry from one syllable to another so
if I go meow cry then i can find that
same place i can find that same release
the same quality and then it helps that
the word is cry and i'm wanting to cry
and be desperate and passionate in my
delivery and you want to put that
sound in there it actually is
it's a nice marriage between lyric
and sound quality lyric and tone here so
if i go
(meow sounds) come on and cry and kind
of get very you know sort of sectioned
off with her almost choppy very spoken
vs thinking about having all the perfect
finesse because i'm still in process i'm
not going to divorce myself from the
process because i'm now singing song
lyrics i still want to have that quality
in there as i get familiar with this way
of singing this phrase (meow sounds)
come on and cry and then slowly
get into the more finesse version the
more legato version of this
come on and cry get myself into the mix
from that sound if that makes sense so
now let's take this up a half step right
here so now the high note is an e come
on meow come on and cry
take things like that like one little
word stop even in the middle of the
phrase if you're like that's not quite
it
(meow sounds) there's my mix okay keep
it that loose you know don't worry about
having this amazing quality to go
through there but (meow sounds)
cry cry and then slowly stretch it
out right
add a little bit of that sort of wild
vibrato and then you know finish it off
as you go down but that's a very simple
way to take what you're doing in the
program and apply it to a song a hard
song too you know whatever it is that
you're listening to whatever it is that
you're trying to sing this is a hard
process and here's the thing about any
of Brett's programs is what you're doing
systematically in a program is not the
most diagnostic part of your journey as
a singer that's really where lessons come
in and it's an
important role to play and in addition
to using 360 or whichever mastering mix
whatever program you're using is get a
coach get somebody to help you unpack
this stuff and really apply it very
specifically to your needs it's not a
one-size-fits-all but all of it does
work when applied appropriately
and correctly to everybody's voice but
sometimes the journey to get there looks
a little bit different i would love to
help you out with that if you're
struggling in this using the program and
trying to figure out application
give us a call I would love to help you
out with that
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FNAF 2 Yamimash Animasyon Türkçe Çeviri (CC) - Duration: 2:19.
For more infomation >> FNAF 2 Yamimash Animasyon Türkçe Çeviri (CC) - Duration: 2:19. -------------------------------------------
Horse Cartoons For Children 3D Horse Colours Colour Song For Kids Colours Horse Cartoons For Kids - Duration: 1:22:05.
Horse Cartoons For Children 3D Horse Colours Colour Song For Kids Colours Horse Cartoons For Kids
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Khalid "Location" Official Lyrics & Meaning | Verified - Duration: 3:52.
Even though the song sounds all...aaahh like it's nice, it's like no this dude is really
going through some shit like he really wants to know if this person is the right person
for them. And maybe they're not.
So he ends up being fucked over eventually.
The loop of the beat like you hear this … I'm like yo run it back, run it back.
It was super catchy so I started rolling with it. I took it back to El Paso reminded me of
this girl I was talking to and then I kind of wanted to impress her so I just finished
the song there.
I didnt tell her it was about her.
She knows it's about her but we dont talk anymore so it's kind of pointless.
Let's focus on communication kinda has to do with breaking down that barrier that we
have because everyone is just so comfortable behind their phones.
Sometimes I feel like as individuals we lack empathy.
Everything's just based off of emojis and text messages and signs and memes and all
that which is dope I mean I still use that shit but at the same time to connect with
someone in the form of intimacy I feel like it's really necessary to just kinda pick
their brain face to face and see their reaction.
I was only in three, two relationships.
She's never been in a relationship in her whole entire life. So, why do I fool with you?
We have no title, no one really knows that we're talking but fuck it I guess we'll
just keep talking.
Just the hint to the whole twitter social media connection, I remember at the time we
were talking to each other it was always she would subtweet me and I would favorite it,
and she would know it was about me.
I would subtweet about her. She would favorite it and we just kept going back and forth between
this I'm like - I'm tired of this shit!
In El Paso we have a lot of spots.
My favorite spot is probably like scenic drive El Paso Texas. You drive all throughout the
mountain, and you can look at waters and you can look over El Paso and just see lights.
A vibe is just you know you're just coastin' you might be ridin down the highway up the
mountain wherever. It's just you feel it, like you feel the vibe.
Just kinda like safety.
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Nella Sings Her 'Fight Song' Music Video | Nella the Princess Knight | Nick Jr. - Duration: 1:01.
NELLA: A princess must be kind and loyal.
[BABY LAUGHING]
A knight must be brave and strong.
I am Nella, the princess knight.
And if my kingdom needs me, I'm always ready to fight
for what's right. (SINGING) This is
my fight song, take-back-my-life song, prove-I'm-all-right song!
Go get him, Nella!
Let's go! (SINGING) My power's turned on!
Starting right now, I'll be strong.
I'll play my fight song.
And I don't really care what nobody else believes.
Gotcha!
(SINGING) Because I've still got a lot of fight left in me!
ANNOUNCER: Get ready to fight for what's
right with "Nella, The Princess Knight."
The brand-new series premieres Monday,
February 6 on Nickelodeon.
You can watch more "Nella, The Princess Knight"
on the free Nick Jr. app.
[NICKELODEON THEME MUSIC]
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Silento - Thinking About You ( Official Audio ) New Song 2017 - Duration: 4:01.
thanks for listening to this i love you `;)
subscribe to my channel for more music :)
Follow
Silento @PRINCESILENTO
Youtube daily make Jan 31 2017
How To Make Paper Origami Fly Origami tutorial and video instruction on how to fold a fly This easy origami fly is simple to make and looks great. If you follow these simple instructions we'll teach you how to make an origami fly, all you need is a sheet of paper.
For more infomation >> How To Make Paper Origami Fly - Origami BEST #origami - Duration: 5:18.-------------------------------------------
Exam Students, Let's Make Concentration Easy Tip #1 - Duration: 7:37.
So you're studying for exams!
The question that I'm asked most is
How can I help myself to concentrate better?
I help thousands of people every year
to concentrate more effectively and efficiently,
to remember more of what they read,
what they hear and what they study.
We make sure that they can bring
that to mind when they need it in their exams!
So if you're interested in the
techniques that I use, I'm going to be
showing 1 simple activity that you can use
to eliminate visual distraction
so that you can focus all of your attention
into your FOCUS ZONE
Your FOCUS ZONE is the space between the top of your head
the of your shoulders and down to your waist.
When you are concentrating and
focusing most of your energy and your attention
attention needs to be focused into this
space because this is where you
hold your book to read this is where you write
this is where you type this is why you do the things
that you need to do in order to study
and to perform in your exams.
If you can bring your attention into this FOCUS ZONE
and keep it there for EXTENDED PERIODS OF TIME
then you will have no difficulty and studying
So the first activity that I help people to do is
is to bring the visual attention in
from their whole visual environment into this space
into their FOCUS ZONE
and to do this all we do is we reassure
your body and your mind and your whole being, in fact,
that you are SAFE in your VISUAL ENVIRONMENT.
We inherited our bodies and the way we operate
and the way that we operate
from our ancestors who were hunter-gatherers!
If they missed a single sign of danger
in their environment it could be catastrophic,
they could lose their life, their family or their food,
but for us in the 21st century
that's not the issue (Thankfully!)
We need to make sure of is that you feel secure wherever you are,
that you feel relaxed,
that you feel comfortable....
When you can feel safe in your environment
then it becomes possible for you to
focus all of your visual attention in here
and to ignore the rest of the visual environment.
To do this we are first going to
check how your eye muscles are working
because, when you are reading
your eyes have to travel over and back
and as you look up and look down
to various different things as you are studying
and if you are called to look up to you need to be
able to look up and look back down again
as long as your vision remains within your FOCUS ZONE
then things are okay
Right now we need to check how well the muscles
of your eyes are working because when
the muscles of your eyes aren't working
well you will start to use your neck
muscles and you find people who are
reading and they're turning the head
rather than moving their eyes
This can be a major strain and stress on your body
it makes you tired very quickly and it
makes you want to switch off
concentrating and studying from the
topic that you're dealing with.
So what we're going to do now is
to check how your eyes are moving
I'm going to invite you to LOOK UP towards your eyebrows
and then LOOK DOWN towards your chin
and look towards one ear
and then look towards the other ear
and just decide yourself which one
of those (directions) felt most strained
Was it (looking )UP Down to this side or the other?
Just write that down for yourself,
notice or just remember it.......
So the first activity we're going to do
involves putting your thumb and two fingers like this.
The distance apart is approximately the same
as the width of your mouth.
So bring it down here onto your chest
under your collar bone
just at the wing tips of your shirt.....
What you want to do is
rub here (under your collarbones )
the other hand is going to rest on your belly-button. (naval)
While we are doing this I'm going to invite you
you to move your eyes slowly all the way
all over to one side....
at eye level if you can
.... and then slowly all the way back....
....go to the other side at eye-level
look towards one ear
and then slowly across
towards the other ear again.
So one loop all the way over and back is one complete cycle
and we will do this three times in total.
Slowly...... slowly send your eyes across all the way
and all the way back slowly, gently
and as you are doing this you may find that you
actually scanning the whole visual horizon.
You are reassuring your brain and your body that you feel safe
and that there is no imminent danger
in your environment.
Next we're going to swap hands
I'm going to invite you just begin at
one (ear either on) this side of the other side
and slowly allow your eyes to go all the
way up towards your eyebrows,
across your forehead, follow all the way towards your ear
down across your cheek, down towards your chin
towards the other cheek,
over towards your ear,
all the way up towards your eyebrow
all the way up along
and anywhere that you find that your eyes are jumping
don't worry about it because we're going
to go around three times in total.
As we are doing this we are scanning the
environment above you and below you,
and we are reassuring the hunter-gatherer within you
that you're not going to be attacked
from the overhanging trees
you're not going to be attacked from the ground
and as a result you can feel safe and secure.
Because you know feel safe and secure within yourself
you are going to find it so much easier to
bring attention into the very center of your FOCUS ZONE
and you are going to find easier to
read and to do other things that will be
involved in studying.
So I'm going to check with you now
Please look towards your eyebrows
and look towards your chin
look towards one ear and thentowards the other ear.
So, is there the same level of strain(as before)
or have your eyes relaxed?
In the comments underneath
please let me know how you got on.
(There will be a new video ) tomorrow which will
help you to clear away the auditory distractions
so that you'll no longer be hearing the outside noises
and you are able to focus and calm down
the hearing and listening inside your head
so that the only thing that you're
hearing is your ( inner )voice as you reading
or your (inner )voice as you are working out the problem that you're solving
Thank you for watching
and as i said in the comments
underneath please LIKE this
and if you are watching this on Youtube
please subscribe and then you'll be notified of
the next video as soon as is launched
Thank you for watching. Visit https://Padraigking.com
-------------------------------------------
Join PBS NOVA on Kickstarter before March 3 to help MAKE SCIENCE FOR ALL - Duration: 5:54.
David Pogue: We're definitely looking at a 20 to 90% chance of… something…
No, no, no.
I was gonna to be on the 8:15 stagecoach to Chicago…
Nurse: Patient's ready, doctor.
Doctor: Handsaw!
What's that for?
It's just a bunion!
( gasp )
Announcer: American students come in 25th on standardized science tests...
Announcer: Cyber terrorism is on the rise, yet only 1 in 4 high schools offer computer classes...
Announcer: 18 percent of Americans think the sun revolves around the earth...
( scream )
Hello, I'm David Pogue.
Former technology columnist for the New York Times…
tech critic for Yahoo...
and the host of 16 programs on NOVA on PBS where I've "heroically" sacrificed my
dignity in the name of science.
Fire!
( screams )
Whoa!
You know—unfortunately, when a lot of people think about science, they picture… this.
Boring Announcer: Well, that's what happens when light is reflected from things.
( snore )
And that's a shame!
Because what scientists know—and science-lovers—is that science is actually more like this!
( cheers )
It's cool and exciting!
( cheers )
And there's a bigger picture, too.
If we're gonna solve the world's problems like curing diseases, feeding the hungry,
finding enough clean energy… we need science.
So, the big question is: How can we get more people to love science?
Well, that's where NOVA comes in.
( NOVA theme music )
For over 40 years, NOVA's mission has been to bring science to life.
It's the most-watched science show on American TV.
It's won countless Emmys, Peabodys, and other awards!
Teachers across the country depend on NOVA to fire up our kids in the classroom.
And NOVA has actually changed lives.
I've met kids who've decided to become scientists and engineers
because of NOVA shows they saw.
We need to make science… for everyone… and through Kickstarter, for the first time,
we see a way to involve as many people as possible in that mission!
Our first goal is to make a new NOVA special — with your help.
It's called Beyond the Elements.
It's actually a follow-up to a show I hosted
in 2012, called Hunting the Elements —
It was a two-hour exploration of the periodic table
told through experiments... explosions...
and adventures.
And explosions.
Over 10 million people watched that show.
Nearly 3 million people downloaded the Elements app
and countless teachers use our online support materials.
We think that's proof that science CAN be for everyone!
So ever since, we've been itching to make another special,
that goes beyond the periodic table, into the secrets of molecules.
There are only about 90 naturally-occurring elements, that can combine in over 100 million ways
to make up… everything we know.
Water.
Air.
DNA.
Coffee.
Styrofoam.
Spray-on cheese…stuff…
We're so excited to make this film!
And that's where you come in.
If we reach our first goal of one million dollars, we'll be able to get started right away
making Beyond the Elements
a 2-hour TV special, that PBS will broadcast on national TV.
At one and a quarter million dollars we'll also
be able to bring Beyond the Elements into the classroom
with additional teaching materials.
Then, it gets even cooler.
If we can hit our third goal, one and half million dollars, we'll be able to go interactive.
We'll create NOVA's very first virtual-reality experience.
Whoa...
Whoa!
Acid molecule – 10 o'clock!
Sorry.
It's just really cool.
You'll see.
Finally, the more we raise above that, the more schools we can help.
Our goal is to send free DVDs of both Elements specials
to every single public high school in America.
At two and a quarter million dollars that's nearly 26,000 schools!
And what do you get out of it?
Well, first of all, you'll be helping NOVA make something huge.
You can also share your input with us.
You can follow along behind-the-scenes the whole way!
And, of course, there will be rewards.
Like t-shirts, posters, and other cool stuff you can only get here.
Or, if you'd rather give unto others, you can help out your favorite science teacher
or a whole school by sending NOVA episodes to spark young imaginations.
And check back often – we'll be adding new stuff all month!
So, that's the plan.
And, look, I know it's a huge goal, but it's so worth doing.
If we work together, we can get more people turned on by science.
We can get more students ready for their technological future.
We can get more humans equipped to tackle the world's challenges.
Let's work together to inspire curiosity about the world.
Let's do this!
Doctor: Saw!
Please!
Give to our Kickstarter!
Please!
-------------------------------------------
Married to Medicine: Never Say Miss Quad Can't Make an Entrance (Season 4, Episode 12) | Bravo - Duration: 1:27.
>> Where's the birthday girl?
>> Now that's always the question.
>> Get ready for the face, the body,
everything about this woman is gorgeous!
Over the top, dramatic.
Ya'll ready, I don't hear ya'll!
Ya'll ready for Miss Quad?
Are ya'll ready for Miss Quad?!
[cheering]
>> That girl is crazy!
>> It's a birthday!
It's a birthday!
Get it Quad, get it!
>> Wow!
>> That's what I'm talking about girl right there!
Show your skin, let it hang out!
Shake, shake, shake, shake!
Happy Birthday bitch!
>> Yeah this is a show.
I mean this is a show.
This is uh-
>> This is a real carnival.
>> Carnival, strip club, everything looks like
it's happening here.
I mean seriously.
>> That's how you keep it spicy!
>> I know to the average eyes it might
seem like wow did she get a choreographer for that?
I was the captain of the majorettes from the
fourth grade to the twelve grade,
it's natural.
-------------------------------------------
Process to make reforms to help abused Texas children begins - Duration: 2:00.
REACHES HIS DESK.THE PROCESS
TO MAKE LONG-LASTING REFORMS
FOR ABUSED AND NEGLECTED TEXAS
CHILDREN HAS JUST BEGUN AT THE
STATE CAPITOL.BUT IT MIGHT
TAKE MORE THAN EXTRA CASH.
DESPITE EMERGENCY FUNDING AT
THE END OF LAST YEAR...THIS
GRAPH SHOWS FLAT PROGRESS IN
GETTING HIGH-PRIORITY CASES
ASSIGNED AND UNDERWAY, FROM
DECEMBER TO THROUGH THE FIRST
FEW WEEKS OF JANUARY.THAT RED
LINE IS REGION 7, WHICH COVERS
CENTRAL TEXAS. POLITICAL
REPORTER PHIL PRAZAN TAKES A
CLOSER LOOK AT THE PROGRESS -
AND THE PROBLEMS STILL FACING
THE AGENCY.LAWMAKERS APPROVED
800 NEW EMPLOYEES LAST
FALL...THE DEPARTMENT OF
FAMILY AND PROTECTIVE SERVICES
HIRED MORE THAN 200 SO FAR.
THOSE DON'T HAVE FULL
CASELOADS YET."WE REALLY NEED
A COMMISSIONER WHO'S GOING TO
STAY THERE TWO, THREE, FOUR,
FIVE, TEN YEARS WOULD BE
IDEAL."WILL FRANCIS FROM THE
NATIONAL ASSOCIATION OF SOCIAL
WORKERS SAYS TO MAKE LASTING
REFORMS, IT WILL TAKE EFFORTS
TO KEEP LEADERS IN PLACE FROM
THE TOP DOWN AND THE MONEY TO
ATTRACT DOWN AND THE MONEY TO
ATTRACT THE BEST WORKFORCE.A
DECADES LONG
PROBLEM, WON'T BE SOLVED IN A
FEW MONTHS."REALLY HAVE TO
INVEST IN A STRONG NUMBER OR
ELSE THE SMALLER DOLLARS, THEY
JUST WON'T HELP.""GIVE THE
AGENCY THE RESOURCES THAT THEY
NEED BUT NOT KEEP DOING THE
SAME THING, BECAUSE THE SAME
THING HASN'T WORKED VERY WELL."
MONDAY, THE HOUSE WORKING
GROUP ON CPS ANNOUNCED A NEW
EFFORT TO MAKE THE DEPARTMENT
REACT FASTER.EVEN THOUGH LAST
SESSION TEXAS EVEN THOUGH LAST
SESSION TEXAS CONSOLIDATED
MANY HEALTH PROGRAMSTHEY WANT
TO DFPS TO BE AUTONOMOUS AND
DECENTRALIZED.'WE NEED TO MAKE
SURE TO GET THIS RIGHT. I AM
VERY CONFIDENT THAT THIS IS A
MUCH BETTER WAY TO DO IT. IT
PROVIDES A MUCH GREATER
OPPORTUNITY OF SUCCESS."BUT
CHILD ADVOCATES WONDER IF DFPS
CAN HANDLE ALL THESE CHANGES
IN THE MIDST OF A CRISIS. PHIL
PRAZAN.KXAN NEWS. BOTH THE
HOUSE AND SENATE BUDGET HAVE
AROUND $260-MILLION ADDITIONAL
DOLLARS DEDICATED TO
DEPARTMENT OF FAMILY AND
PROTECTIVE SERVICES.THE AGENCY
-------------------------------------------
how to make money from youtube bangla tutorial,computer generation,part 1 2017 - Duration: 21:33.
For more infomation >> how to make money from youtube bangla tutorial,computer generation,part 1 2017 - Duration: 21:33. -------------------------------------------
How To Make a Beautiful Pot for Plant | DIY - Duration: 5:35.
How To Make a Beautiful Pot for Plant | DIY
How To Make a Beautiful Pot for Plant | DIY
-------------------------------------------
5 Tips to Make Your Long Distance Relationship Last - Duration: 5:22.
They say that absence makes the heart grow fonder, but that doesn't mean it's easy
to be away from your lover...
Hey YouTube, my name is Amy North and I'm a relationship coach from the west coast of
Canada.
Today I want to talk about something that I get asked often, and that's how to survive
the distance and have a strong, healthy relationship.
Now, I know first hand that long distance relationships aren't easy, I've been there
before and I must say, it does take commitment and dedication to keep your spark alive.
That said, the tips I'm about to share with you do help keep you and your man close, despite
the miles between you.
Before I do so I'd just like to quickly ask that if you enjoy what you learn here
today then please show your support by subscribing to my YouTube channel.
There you'll find more dating advice, and other tips for a loving, lasting relationship.
Now, let's jump into my five tips for making your long distance relationship last.
1.
Have an end date in mind.
One of the hardest things about being away from your partner is not knowing when you'll
see each other again.
Why?
Because it leaves room for the imagination to run wild, and if you start doubting your
relationship, it's a tough spot to get out of.
Instead make plans with your partner, and know when you will see each other next.
Whether that means planning a visit for months down the road, or seeing each other on the
weekends, whatever the case, simply having an idea of when you're been together again
does make the distance more doable, and you'll feel more connected.
When you are together be sure to decide when you'll see each other next.
After all, saying goodbye is a lot easier when you already have another trip to look
forward to.
Of course this can be easier said than done, but if you're both seriously committed to
the relationship, then you should be able to come up with a plan between you.
2.
Send your partner reminders
It's easy to tell your man that you love or miss him, but since actions speak louder
than words, showing him that he's on your mind is a great way to stay connected.
And these don't have to be grand gestures either.
Sure, a surprise package or letter in the mail is nice, but something as simple as a
"good morning" or "good night" text also speaks volumes.
It's these little reminders that will keep you on your man's mind, and vice versa.
For some powerful ways to show your man that you love and appreciate him visit my website,
www.coachnorth.com and watch the free video presentation.
There I share tips that will not only strengthen your relationship, but they'll also help
to keep the spark alive.
I'll be sure to post the URL in the description below.
3.
Make time for one another.
This is a bit of an obvious one, but setting aside time for your partner is crucial to
making your long distance relationship last.
Sure, schedules can be conflicting, especially if you're living in different time zones,
but as the saying goes, if there's a will there's a way!
To do this, talk to your partner and compare schedules to set up "dates" for phone
or even skype calls.
Just as you would go on dates if you were in the same town or city, keep making time
for each other.
If you find that things are getting stale then switch up your routine.
Instead of settling for casual calls you could decide that every Sunday night you both enjoy
a glass of wine while video chatting.
Or, you could play an online game together, or Skype and watch a movie at the same time.
Keeping things interesting is not only a great way to pass the time you spend apart, but
it saves you from having the same old "I miss you" chats.
4.
Stay positive
It's normal to miss your man, but if you let your emotions get the best of you you're
going to start sabotaging your relationship.
If you start letting negativity seep into your relationship, then slowly but surely,
your man won't be as excited to talk to you.
Why?
Because no one wants to listen to someone who's always complaining or upset.
As tough as it may be, it's crucial that you do your best to stay positive.
Yes, the waiting can be painful but you need to remind yourself that in the end it will
be worth it.
One good trick to staying positive is to be grateful all the time.
Be thankful that you have someone to love and someone who also loves you back.
Be thankful for the little things, like the sweet text messages he sends you or the daily
check ins.
It can be hard to master, and there's no doubt that you'll have tough days, but remember,
positivity will keep your relationship loving and strong.
5.
Avoid jealousy!
Just because you can't spend time with your man, you can't expect him to isolate himself
from the rest of the world.
In fact, you should encourage him to keep busy — when he's preoccupied it'll give
him less time to sit around missing you, which as much as it may sound romantic, will end
up doing more harm than good.
That said, when your man is spending time with others it's important that you remain
supportive and don't get jealous.
Even if his plans involve women you don't know, trust him enough to be his own person.
If you get defensive anytime he's around other ladies, he'll assume it's because
you're not being faithful when you're around other men.
Or at the very least you'll come across as insecure.
On the other hand, if you're okay with it, you automatically seem more trustworthy and
confident.
So simply put, keep your cool.
Well that does it for this video, thanks so much for watching.
If you have any questions about what I've covered then please post those in the comments
section below.
Or, if you have tips for making a long distance relationship last then share those too, I'd
love to hear them!
Again, if you enjoyed this video then please do me a huge favour and subscribe to my channel.
Your support allows me to keep coming out with videos, so really it's a win-win for
both of us!
Until next time take care and good luck!
-------------------------------------------
Go with the flow Make Up + Blabla | Juliette A. Make Up - Duration: 7:26.
Hey hey, amigos! I hope you're doing good.
I wish you an awesome new year!
Full of wonders and mounts and wonders...
full of beauties, of glitters, of marshmallows...
... full of facepaint, of liquid latex ... aaand...
Cotton!
At the time, I record it...
As you see me talking to you right now...
I don't what I'm gonna do
It's the compleeete mystery!
The concept is, I play some music on my laptop
And then, let myself carried away by the music...
... and colors!
I'll play some musics I've listened to while facepainting.
And I'll add a voice over with my soft and sweet voice.
To talk about the channel and what I'd like to do in it.
If you like the content, you can leave a thumb up
or a comment to tell me what you think
Also, you can subscribe!
By hit the subscribe button.
It's pleasing! It's free! There's nothing to lose!
But It feels good!
I send big kisses and say see you soon!
First, I'll tell you about the artist i chose for this make up.
It's Sona Jobarteh.
She's a gambian singer, composer
and instrumentalist.
Born in London.
She plays kora, a string instrument from west Africa
Her father is an artist too
who has a band that plays same kind of music.
I actually discovered the band while recording,
as I let youtube runs after playing the first music.
Links for most songs are in the description!
If you're curious and want to have a try!
Don't hesitate, it's good stuff!
I only picked samples of 3 songs
to give you a little preview of this artist.
This song is "Gambia".
Next one is "Jarabi".
And the last one is "Musow".
Songs in the description down below. ;)
I wanted to tell you about a project I have,
I called it "Subtitle's Mission"!
Indeed...
I'd like to subtitle my videos in english!
I'd like that to attract more people on my vid
and make it understandable to more people!
And also for my english speaker friend...
... Because, yes, I have english speaker friends!
To make friends understand what I do
and have feedbacks also from them.
All videos are concerned!
From the oldies to the next ones coming.
For that, I need your help!
Yes, you there, behind your screen!
You!
And you!
And you!
Anyone good enough to translate french-english!
You can help!
You can contribute to this big projet.
It's pretty big...
Because it's not easy to translate
and place the subtitles at the right timing!
If you're interested in helping me,
there's a link for that right at the start in the description.
The link takes to a page with the video and everything you need.
Then I have a look at it.
I check
I modify or not
And I validate or not.
If you could do it...
even just a word...
1 or 2 sentences...
It'd help me a lot!
Now it's up to you , guys and girls!
And little contribution would be pleasing too...
-------------------------------------------
How To Make Your Vag Tighter - Vigina Tightening Home Remedies - Duration: 2:11.
How to Tighten a Loose Vagina naturally at home.
Loose vagina is a common health disorder in women, which can affect the intimate relationships
between couples.
Moreover, a tight vagina is indeed very important for a woman because, it is advantageous both,
sexually and otherwise.
To get rid of this problem here are best 3 ways which can help you.
So Click the subscribe button for more videos.
1.
Aloe Vera.
The freshly extracted gel of aloe Vera plant can be very helpful in making your vaginal
muscles tighter.
Take a large aloe leaf and scoop out the gel from it.
All you need to do is apply around 2 tablespoons of this fresh gel to both external and internal
parts of your vagina every day.
Massage the skin of the affected area with it or simply rub it with your fingers in a
gentle manner.
Doing it every day will increase the elasticity of your vaginal muscle sand make the area
tighter.
2.
Gooseberries.
Gooseberry, especially Indian gooseberry or Alma, is known to be one of the best natural
solutions for tightening vagina walls.
Take 10 to 12 gooseberries and boil them properly in plain water and store the resultant solution
in a bottle.
Apply some over your vagina when you take a bath every day.
The solution would restore the elasticity and suppleness of your vagina in no time at
all.
3.
Mint leaves.
Take 8 to 10 fresh and tender mint leaves and boil them in 1 liter of water.
After that, pour this solution in a bucket and sit on that bucket so that the steam reaches
inside your private region.
Ensure that this mint solution is not too hot.
After following this home remedy to tighten loose vagina, one will observe the tightening
effects as soon as within 15 minutes.
-------------------------------------------
A woman without make up - Duration: 0:27.
For more infomation >> A woman without make up - Duration: 0:27. -------------------------------------------
How to make box,envelope and wallet from paper - Duration: 0:52.
Hello dear friends
How are you In my next videos I will show you to make a lot of things from paper
Please subscribe my channel and like my videos
Thank you for watching
See you soon
Best wishes
-------------------------------------------
Did Blizzard Really Make Mei Skinnier? - Duration: 6:35.
Mei has become a poster-child for thick women everywhere
and now with this Lunar New Year legendary
skin, people are a little upset. They seem FOOLED that Mei isn't as skinny as they once
thought. And Blizzard themselves had some choice words about it that don't seem entirely truthful...
Might I start by saying all these lunar new year skins are fantastic? Chinese New Year
isn't really a holiday they HAD to do considering they JUST did a winter event. Most of the
Lunar New Year skins were met with praise from the community. Hot Xenyata is a thing.
Cause he has a face now. I guess people feel like they can ship him with other characters
better now? I don't know.
ANYWAY people have a problem with Mei's skin because of course they do. There was a community
post titled "where did Mei's waist go?" The top post reads "Her regular suit seems like
a tight enough fit on her but her Chinese New Year one her bust and waist are totally
slimmed down. We can have fat as fuck Roadhog and love him so why can't we have fat Mei?"
I like the comment right under it "Because you need to stop focusing on Mei's weight
and move the payload."
So what gives? I think the obvious answer is that she's wearing a big heavy jacket in
her regular skin. She even has a belt full of thick pouches around her waist so this
adds a ton more weight to her mid section. It definitely bulks up her silhouette. In
the Chinese New Year skin she's wearing thin material and a thin belt. It DOES look like
it's squeezing her pretty tight there, but that's just because all of the lines curve
inward, and out of that waist area. There's a side profile floating around comparing the
new skin to her fire fighter skin. There's definitely a lot more thickness there in the
fire fighter skin. I think it's important to note that this is a fire fighter outfit.
And those are thick as hell. It's thicker EVERYWHERE on her body. I do not think it
was intentional to make Mei appear any skinnier than she did previously. She literally just
took her jacket off. That's it.
In the original concept designs for Mei she does look skinny.
I know these are just concepts and they don't necessarily reflect the final product but,
she's skinny here. These are some ideas from the artists. I shouldn't say skinny but there is an hour glass goin' on.
UNTIL BLIZZARD RESPONDED to that forum post from earlier. A community manager said, "There's
a bug with Mei's Luna and Chang'e skins right now that's causing her waist to appear much
smaller than normal. We've already fixed the bug internally, but it's going to require
a patch to implement (ideally it'll be included in whatever next patch hits your gaming platform)."
That seems like a whole load of horse shit to me. I find it very hard to believe that
this is a bug. This is an artist's vision of what this character would look like without
all that gear on. People just don't like it and want her to be fatter. I don't think it's
going to stop anybody from playing the game. But fine, if you want to appease the fans
go right ahead. Calling it a "bug" is a little much though. Could just say you fucked up.
Blizzard has a history with responding to
criticism like this and making changes to the game because of it. There's the infamous
sexy Tracer pose that got replaced by a slightly less sexy but still pretty sexy Tracer pose.
Players even took issue with Mei's skin in the Winter Wonderland event. In a post titled
"Blizzard, please give an answer to the Mei skin." a user stated "It's clear that the
majority of people do not like that skin, and feel that it is inferior to all of the
other legendary skins in the game. Someone from Blizzard needs to respond to the criticism
of the Mei skin, and clarify what exactly defines a legendary skin. This skin is probably
going to be the last Mei legendary skin we get for awhile. A long while. If Mei was the
last hero to get a skin since launch, then I shudder to think how long it'll be until
we get our next one. A lot of people are concerned that this will be her only new skin for a
long time, and it's (as decided by the community) quite a disappointing one." Remember, these
are free updates. Blizzard doesn't have to do any of this. And for the record, I don't
think there's anything wrong with her holiday skin. It's Christmas-y, maybe people took
issue with that?
In this case it was Game Director Jeff Kaplan who responded, saying "Sorry you are disappointed
with Mei's winter skin. We don't have a specific rule for what makes something Legendary
or Epic. We just sort of make a gut call based off of what we think is cool. Coolness is
very subjective, and based off of the community reaction it seems like our gauge was off on
this one." This part is great. "For people concerned that Mei is not going to get another
Legendary for a long time, you need not worry. We have something pretty awesome for her early
next year." HA.
Oh Jeff Kaplan you were so young then...
...one month ago...
I think he hit the nail on the head right there. "Coolness is very subjective." I align
myself with Steve Job's theory that people don't know what they want, they just have
to be handed something they'll like. And not everybody is going to like what you have to
offer. You can't please everybody. It's great that Blizzard is active in their community,
but you don't need to make excuses for yourself. Your product is good. People are going to
keep playing.
Now if you wanna fix Mei, nerf the FUCK out of her so her ICE SHIELD stops blocking my
HIGH NOON.
(End slate stuff.)
(Subscribe. Watch THE ART. Tune in to Wulff Den Live on Wednesday Nights at 9PM. Blah blah blah...)
(Oh yeah and comment something stupid...)
(If you see this just write "tits")
(And if you see this write Pikmin sucks.)
-------------------------------------------
How to Make Big Digital Pattern / Template for DIY Projects!! | I Wear A Bow - Duration: 4:56.
Yes I'm in my pajamas right now.
Hi! I am Bonita!
So today we're going to learn how to make this big digital pattern that you can use
For anything, any projects like sewing, DIY project, or any craft project, or maybe room decor, anything! Just any.. any other things.. yeah..(?)
I learned it from Karen Kavett. So go check her video for the original lesson!
I will leave the link in the description box below or check this cards above, or at my right
This way, this way, this way.. yeah
So I won't keep this intro long, let's start the fun!
Let's open the photoshop.
Make new file, and I like to make the size in inches.
For the size is up to you.
It depends on how big you want your pattern is.
For this tutorial, I want to make a pattern that is approximately twice the size of A4
paper.
So hence mine is 15 inches and 20 inches.
Also make sure the resolution is 300 pixels.
Okay.
I want to make a star pattern, so I use this polygon tool.
Double click the canvas and it will open the settings.
Activate the star option, number of sides 5, and I like my indent sides by 30%.
Just ignore the width and height now.
It automatically made a small star.
I want a big star, so I deleted it.
Then click and drag on the canvas to make a big star.
Move it to the center.
And click ctrl+T to activate the Transform tool.
And then readjust the size.
Click Shift while you adjust it, so it will link the width and height.
Next right click the polygon layer and click rasterize layer.
Then I fill the star with black.
Now make another file with less than A4 paper size so it won't be cut when we will print
it later.
Like 7.5 inches and 10 inches.
Select all and then copy it, to the star file.
Then change the color with any contrasting color.
Move it to the corner.
And then copy it and move it the side.
And change the color with any other color so we can see the difference.
Copy it again and move it.
Just do it until it's full.
Now use magic wand tool, and click the first rectangle layer and make selection of it.
Now click the polygon layer and click ctrl+c to copy it.
And paste it to here.
Do this with another rectangle so we can copy all parts of star shape.
After that, deactivate these layer so we can see just one layer.
Now click blending options, and make the fill opacity zero.
Now add stroke in the inside position.
And the size is up to you.
Use black for printing.
And just right click and copy this layer style and paste it to other star layers.
Now if you activate the eyes you can see it's already like these.
Deactivate it again to save the star parts one by one.
Now it's up to you wheter you want it as JPEG or PDF.
For me, I like PDF for printing.
So yeah save it.
Star pattern part 1.
Okay.
And do it with other layers.
Save them.
Now this is how it turned out.
Now if you want to print it, dont't choose fit, choose actual size or shrink oversized
pages.
And then see the page setup and change it to A4 paper because my paper is A4.
And print.
Now after cut all the parts.
It's just a matter of assemble all of these like a puzzle, Karen said.
Then use tape to stick them together. And done!
So how we're going to use this?
Next video, so stay tuned!
So that is it for this video! If you found this video helpful, share this video!
And as always I will send you lotsa lotsa lotsa lots of love, peace, and courage. Bye and have a wonderful day!
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Until I Make U Smile - Duration: 6:31.
For more infomation >> Until I Make U Smile - Duration: 6:31. -------------------------------------------
eToro - How to make up to 10,000$ mounthly - Duration: 1:16.
For more infomation >> eToro - How to make up to 10,000$ mounthly - Duration: 1:16. -------------------------------------------
Convenience of gift cards make them easy target of thieves - Duration: 2:09.
LOTS OF PEOPLE BUY AND RECEIVE
GIFT
CARDS .. BUT THIEVES ALSO LIKE
THEM.
BETTER BUSINESS BUREAU...
... ABOUT HOW AVOID BECOMING A
VICTIM OF
A GIFT CARD SCAM.
You can find them just about
everywhere... and
they're easy and convenient gift
ideas. But
they've also become the target
of thieves.
One of the things when you get a
gift card, you
want to look at the back of it
and make sure that
the back of the gift card hasn't
been scratched off
Most gift cards have a three or
four digit PIN
under a silver scratch-off, used
to help verify a
card's balance.
Criminals could scratch off the
PIN number and
have recorded the gift card
numbers as well as
the PIN. That's the only
information they would
need to steal whatever balance
may have been
placed on that gift card. They
could check it over
and over and over until that
gift card is sold
As far as getting your money
back if you've
become a victim... Dunn says
don't count on it.
If you purchase it with that
card number already
scratched off then essentially
it's going to be
your word against the merchant's
in terms of
who's responsible
If you're buying a gift card,
you want to make
sure that the silver scratch-off
is in tact
Dunn says businesses can also do
their part to
secured especially
if it's something that we've
identified at a particular
store there's a pattern where
this has happened.
We know if some merchants that
keep
those cards completely locked up
and secured
and audited so they understand
how many
cards they have, what employees
have access
to them
If you have a consumer concern
or are interested
in becoming an Action Line
volunteer, give us a
call at 591-0222 weekdays
between 11
to actionline@khon2.com.
Sean Ibara, KHON2 News.
-------------------------------------------
Make Ethyl Propionate by Fischer Esterfication and Molecular Sieves with a Soxhlet extractor - Duration: 9:18.
Warning: Sulfuric and propionic acids are corrosive.
Wear gloves when handling them.
Ethanol is highly flammable.
Fire safety protocols must be in place.
Greetings fellow nerds.
I wanted to make more ethyl propionate so i'd have a good stock available in case i made more mistakes in my synthesis of pyrimethamine.
Now in a previous video we made ethyl propionate by the classic process of acid catalyzed fischer esterification between ethanol and propionic acid.
If you want to review that video you can check the video description.
The drawback of that method was that our raw yield was about 40% and that was likely inflated since we hadn't purified by distillation yet.
The reason why the yield was low was because the reaction is reversible.
The water can react with the ethyl propionate and produce propionic acid and ethanol again.
If we could remove the water we could drive the reaction forward.
Unfortunately we can't just distill the water out because the ethanol and the ethyl propionate azeotropes have even lower boiling points.
We'd never be able to selectively remove just the water.
We'd also carry out too much of our reactants and stop the reaction.
Now in a previous video i showed that we could use molecular sieves to dry alcohol
and some have asked if that could be used for fischer esterification.
Unfortunately we can't add the molecular sieves directly because the acids in the reaction would destroy them.
Luckily, for us, there is a workaround.
In a previous video I showed this apparatus, the soxhlet extractor.
For further information about it you can check the video description.
But briefly it allows us to condense vapor, dissolve or expose something to that condensate,
and then return the dissolved substance to the boiling flask.
In this video we're going to use it instead to selectively remove water with molecular sieves.
First we start with a erlenmeyer flask and add in 80 mL of propionic acid.
Then we add to that 100 mL of ethanol.
Normally you would remove any dissolved water first but in this case we don't have to as we'll be removing the water during our reaction.
Finally we need an acid catalyst and we'll use 4 mL of concentrated sulfuric acid.
The process so far is just like regular fischer esterification.
Now for the important difference, instead of a simple reflux apparatus,
we set up a soxhlet apparatus filled with molecular sieves 3A.
I have about 80 grams worth.
Mine is bagged with filter paper to prevent the beads from being sucked through the siphon tube and falling into the boiling flask.
The molecular sieves were previously dried on a hot plate at 250 celsius for three hours.
Now the amount of molecular sieves you have limits the size of your reaction.
Molecular sieves can hold about 22% of their mass in water.
So you have to calculate how much mass water that is and size your reaction to produce a roughly equal amount.
You also have to ensure you have enough volatile solvents to fill your soxhlet extractor.
If it doesn't fill high enough to activate the soxhlet siphon then the solvents won't properly return when they are dried.
I sized the quantity of chemicals earlier to match what i'm using here.
Okay once the apparatus is all assembled and the cooling water running, turn on the hotplate.
Gradually raise the temperature until it starts to reflux and condense into the soxhlet extractor.
You don't need a very high turnover rate.
What's happening is we're reacting the propionic acid with ethanol to form ethyl propionate and water.
The sulfuric acid acts as a catalyst.
Now as said before, the reaction is reversible so we can never get a good yield just at equilibrium.
The water reacts with the ethyl propionate and goes back to ethanol and propionic acid.
The soxhlet extractor helps us get around this.
The boiling mixture of ethanol, propionic acid, ethyl propionate and water forms low boiling azeotropes that rise up and condense into the soxhlet apparatus.
For those of you that don't know, or missed my video on fractional distillation, azeotropes are mixtures that boil together.
They behave almost like pure chemicals in that they boil and condense with the same composition.
You can't separate them by distillation alone.
Now i don't exactly know what azeotrope compositions form here.
Water and ethanol make one azeotrope but i found no data on ethyl propionate and the azeotropes it forms.
Whatever it is, I'm betting the the lowest boiling azeotrope between all three contains water.
Even if it's just a few percent water that's tremendously advantageous to us.
Molecular sieves are extremely good at extracting water from organic solvents
so any ethanol or ethyl propionate that condensed would be thoroughly dried and then returned to the boiling flask.
Where it reboils along with a bit more water.
By cycling the water, alcohols and esters around with the extractor,
we can gradually remove all the water and only the water,
without losing our alcohol or esters as we would if we just went with straight distillation.
It's a great trick, the only drawback is that it won't work if none of the low boiling azeotropes contain water.
Now at this point you might be wondering what happens with the acids.
Propionic acid and sulfuric acid are too polar and too high boiling so they don't vaporize and condense into the soxhlet apparatus.
This is very convenient for us as molecular sieves are destroyed by acids.
Thanks to the soxhlet extractor we can use them for the reaction without actually using them in the reaction.
In a way, we've built a mini chemical plant where we have two separate processes running.
Fischer esterification here, and water removal over here.
Anyway, I'll let this run overnight.
While molecular sieves are very effective they are also very slow and need time to work.
Okay here we are the next day and i've already turned off the heating.
Once it's cooled, we pour 100 ml of cold water into the soxhlet extractor.
This is to wash out the alcohol and ethyl propionate from the sieves for greater recovery.
Now give it a stir.
The water will now dissolve most of the components in our reaction mixture except ethyl propionate
which has very low solubility in water.
The ethyl propionate will then float on top like an oil allowing for convenient separation.
To do this we use a separatory funnel.
You can see the layer of ethyl propionate floating on top of the water.
Drain away the water first and then collect the ethyl propionate.
Now you might be wondering why i'm washing with water when i said water destroys ethyl propionate.
While the mixture is cold the reaction of water and ethyl propionate is very slow.
It's only when it's hot that the reverse reaction becomes a problem.
Nonetheless, when i store this i'll be sure to remove all traces of water.
And there it is, crude ethyl propionate.
The mass of this is 103g for a crude yield of 93%.
This is a tremendous improvement over the direct method that only gave 40%.
Now granted, this 93% is grossly impure, but so was the 40% of the original method so we can still compare them.
To improve purity somewhat i'm going to wash it again with 100mL of cold water.
The most likely impurity is ethanol which, while soluble in water is also soluble in ethyl propionate
and usually doesn't wash out in a single run.
Let me separate them out again.
And there we go.
This is 90g or about 81% yield.
We're still ahead of the original method.
Now i'm going to store my crude ethyl propionate over molecular sieves to remove the water.
In my future experiments i'll need it water free.
There is likely still a few percent ethanol remaining but that isn't an issue for what i want it for.
If you want to remove the ethanol you can fractionally distill the ethyl propionate.
In anycase i'm actually quite pleased with how well the soxhlet extractor with molecular sieves worked.
My bet that water was in the low boiling azeotrope paid off.
And this procedure wasn't even optimized yet.
I used twice as much ethanol as necessary because i was roughly copying the old method.
If the water is so effectively removed then we don't need an excess of ethanol.
A stoichiometric amount might work better and give even higher recoverable yield.
Yet another option would be to use an excess of propionic acid and have complete conversion of ethanol.
With no water or ethanol present one could directly fractionally distill pure ethyl propionate from the mixture.
No need for water washing and additional molecular sieve drying.
So many options are available.
This procedure doesn't waste any new chemicals either, the molecular sieves used in the soxhlet extractor can be dried and reused.
This is what i love about having a new tool for chemistry.
The tool itself might change just a single step.
But it can radically change your procedures in ways that open up whole new pathways.
I wish i had more time to try out all these new pathways but i need to move on to my next experiment.
Anyway, so that was how you use a soxhlet extractor and molecular sieves to drive forward the fischer esterification of ethanol and propionic acid.
Thanks for watching.
Special thank you to all of my supporters on patreon for making these science videos possible
with their donations and their direction.
If you are not currently a patron, but like to support the continued production of science videos like this one,
then check out my patreon page here or in the video description.
I really appreciate any and all support.
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